How does your mketer react to the bouncing current draw from the starter and are you going to disconnect the coils so you can run the stater to steady state? There are all kinds of variables you are introducing into the mix.
Self-discharge and surface charge are two distinctly different things but both manifest themselves as voltages.
So when your voltage drops after taking it off the charger, is it the elimination of surface charge and how much of it is self-discharge?
To be clear surface charge represents a state of the battery where it exhibits considerably larger internal impedance. For example, when you first pull the battery off the charger it is probably above 13V. But once you pull a small amount of current, that so-called surface charge of the battery is removed and the voltage drops to a more normal 12.8V. At that point, you can put a larger load on the battery but per unit of current you are drawing, you won't pull the voltage down as much.
In the scheme of things this is a secondary effect but certainly, one that will corrupt your sell discharge based measurements. The point is that dealing in small current loads does not make the State of charge observable because you are trying to infer SOC from small voltage changes affected by secondary effects.
You put a 10 amps load on the battery and there effects are irrelevant and you get an immediate result.
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