http://auto.howstuffworks.com/question90.htm
Notice where it says "or some other combination of fuels that has the same performance of the 87/13 combination of octane/heptane". Since the refining process of crude oil cannot completely separate all the hydrocarbons into pure octane and pure heptane. Gasoline typically is a blend of many different hydrocarbons, alcohols, detergents and solvents to keep your engine clean and running well. The Octane rating on the pump is more often a comparison of the gasoline's performance to an actual octane/heptane solution produced in a laboratory.
My Organic chemistry professor in college explained all this to us, but since it was a 9:00 class, I wasn't completely awake most of the time. And since I never took great notes, I could be wrong. I'm still reading the articles on howstuffworks.com. I may post back with an update... 8)
To be understood is that aviation fuel is not accurately graded by octane rating, it is a performance rating. Nevertheless, it does what it does rather well. I will refer to "octane" here because that is what the fuel trucks are labelled as, and what it's called in the industry.
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