Big T. History is as follows: bike bought as a 1980 unit, in a complete mess. Engine completely rebuilt, carbs u/sonically cleaned (many times!). Carbs set with standard jets, std airbox, 4-2 Jarma exhaust,810 cc conversion/re-bore, float height set to std 22.5mm.. Engine difficult to start, running massively rich. Finaly got it running reasonably well reducing the fuel mix by blocking parts of the pilot fuel system, reducing main jets to 95 and pilots to minimum available size, fitting K&N pod filters, new carb/cylinder inlet stubs and new exhaust gaskets used. No obvious air leaks. Carbs do not flood or overflow. Fuel tank cleaned, fuel tap/cock cleaned and refitted along with in line fuel filter. No sign of debris in the fuel or carb bodies. Carbs are Mikuni VM22.choke mechanism set up as per workshop manual. Now starts reluctantly on choke, quickly runs without choke. Once running motor pulls really well, ticks over OK and seems to run fine but spark plugs still indicate rich running. Also restarts from hot ok. Hence my query as to if another carb type would improve things
Wow. This just makes my head hurt. I'll try to unpack your carb settings though.
The 1980 GS750 had CV carbs, so that can't be right. Earlier VM carbs won't fit the 1980 head. Carbs should be Mikuni VM26 or BS32. VM22 are for the GS550. I will assume you have VM26. If you have BS32, ignore everything here, as those new-fangled CV carbs confuse my feeble brain.
22.5mm is way too low for float height, so it's no wonder the bike ran massively rich. Surprising that it didn't flood. Stock float height for 78-79 GS750 and the earliest GS850 (which used VM26 carbs) is 24mm. Float height affects the mix in all circuits, so everything else you did seemed to overcompensate a bad float height setting. Such as . . .
You blocked part of the pilot system . . . and added pod filters . . . and reduced the main jets???
Um, that makes no sense. With pod filters, you have more air, so you need to increase the mains and other jets (once you have a good float height).
Not sure what effects that aftermarket 4-2 pipe has. Is it freer flowing than the stock 4-2? Akin to the 4-1 pipes? If so, then you should approach the jetting like the typical pods/pipe crowd (we aren't all clowns

).
Those specs are close but not identical. You will find them
here.
The stock jetting for the VM26 carbs for a 750/850 are:
Main 100/102.5
Pilot 15/15
Stock needle setting was either 3d or 2d from top.
With pods and a more open pipe, you need to add fuel to the mixture. You might be able to get the pilot right with stock 15s and some adjustment to the screws, but pick up some 17.5 pilots in case you run out of adjustment range.
You needle will need to go up (richer). Start with it in the 4th slot down. You may need to shim it more, but I doubt you'll end up in the 5th slot.
For mains, you will need to go up a few sizes from stock. Start with jets in the 117.5 range (so grab some 115, 117.5, 120 and maybe 122.5). Be prepared to swap up or down.
Before you begin the jetting saga, strip and dip the carbs and put in fresh o-rings for the screws, choke assemblies, etc. Rob Barr has a complete set for you. Also, clean and re-oil (lightly) those K&N pods. If you got the bike to run at all with those jets, I wager those pods are smothered in oil.
Bored out to 810, I suspect your jetting baseline is in the same neighborhood as my 750/850. For reference, after LOTS of trial-and-error (mostly error

), I am reasonably pleased with my jetting, as follows:
Pilot 17.5
Fuel Screw - 7/8 to 1 turn out
Air Screw - 2 turns out
Needle - 4th slot + 4 #3 washers for a tiny shim.
Mains - 117.5
The only part I am not certain about in my jetting is the mains, because city riding does not put me in WoT enough to be sure.